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I will Not point Female Fingers here, dear, But perhaps it is The Best from the Rest Place to talk to from This... Place.
He may be a Workaholic and the time that is the most Private with him is when he is 'In the office' and even On... Weekends.
Have a Serious Soul mate convo with him about your Relationship and find out if there could be More in Store.
In Regards to a LDR, I still have a husband out in Egypt and when we would be doing Skype, The Best time for me to talk with him, For we were 6 hours apart, Was around 3Pm in the afternoon and in my Room on my Laptop.
Good luck. xx0