It's from "Freaks and Geeks" by Childish Gambino."You get sloppy drunk, I stay whiskey neat."
It's a pun - whiskey neat is whiskey without any ice or anything else in it, but obviously the 'neat' also contrasts with the 'sloppy'. Just a somewhat clever way of saying that the singer is better than the other person and more controlled.
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It's a pun on one of the ways to order whiskey in a bar.
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