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Harley Quinn (Joker's psychotic gf) has always been blonde in the comic books and on Batman's animated series as long as I can remember.
Aren't most of them bald or Aryan?
Captain Nazi, he is one of Captain Marvel's enemies
Emma Frost, When was a villain
i dont watch superhero movies that much but i have watched some here and there when i was younger, and its crazy because i've also noticed how for some reason the villains usually tend to have dark features.
Here are some from Marvel:
Black Widow (Yelena Belova)
Agent Venom, prior joining SHIELD.