Why do guys go after married women?

mickey1016
I like this guy (31) at work and he just recently got a divorce and has three kids. we work at a gym.
Whenever this one girl (25) comes in he is always with her and seems to be flirting. But she is currently married with three kids.
Is it just the thrill of wanting something you can't have?
Why do guys go after married women?
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