This is kind of what my boyfriend did too. I would get to class and he'd be sitting next to where I always sat, make small-talk about class like if I did the hw, how much of a bitch the professor is lol, etc. Like Nicole said if the girls responds back with more than one word answers or is smiling or laughing or whatever, you can keep talking to her more like I'd walk into class listening to music and he'd ask what I'm listening to, something like that. Then suggest studying together for an exam
or whatever and get to know her from there!
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