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I personally have no interest in going after girls with bf's. Not because I'm morally opposed or anything, but because it is like 10 times harder than going after a single girl. Just today I asked a girl out as her bf walked up to us, (look at my recent questions for more info). If this is what you want, then fucking do it. You can wait to see if she breaks up with him (meanwhile working your charm so she's ready for you when it happens). Or you can try to get her while she's still with him. This is survival of the fittest at its finest, it's fucking beautiful and natural. Good luck man.