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Yes, you could ask him if he is gay or a religious zealot.. If he isn't one of those two, he is trying to f*** you. If the sex is good and he has plenty of it, he may hang around long enough to get too like you. I know that sounds harsh, but that is the way of the world. :)
I'm not sure if this is what you are looking for but I would say make them wait. If they aren't willing to wait a while for sex, they don't really care about you.