How do I play it cool?

Ok so i have had this huge crush on this man who comes into my work quite often. For over a year. I asked him a few months or so ago if he was single and he wasn't (i was pretty bummed, and a little embarrassed putting myself out there like that but i thought it was worth a shot ) and i respected that he wasn't, so i dismissed the chance or hopes of dating him. Well i ran in to him again and he gave me his phone number and told me he is getting a divorce. He seems a little sad? Maybe or just upset (divorce does suck) I genuinely feel bad for him he's such a sweet and attractive man. Am i able to be his friend and just be encouraging in this difficult time or is that wrong because i have a desire to be with him? Any advice or thoughts would be appreciated thanks guys
How do I play it cool?
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