Most Helpful Guy
I'm not a big fan of that outfit on the picture since it looks a bit lazy. But you can't tell a person's sexuality based on their clothing. Not every lesbians are masculine and not every gay men are feminine. It's just a stereotype people made up.
But women can look good in masculine outfits like this:
So yes, women and men can look good in men's wears if the outfit looks good. Just my opinion.
Most Helpful Girl
That's not something I would wear or like. But I'm more girly