Will I most likely get a job if I’m friends with the CEO and she referred me?

This is in tech. I have years as a software engineer and we worked together in the past and used to hang out.
She told me they create opportunistic roles that aren’t on the website so it sounds like she wouldn’t have told me about this if she wasn’t interested.

Will I most likely get a job if I’m friends with the CEO and she referred me?
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