Could be that she doesn't want to add you because she doesn't like you for whatever reason or doesn't want to lead you on by adding you thinking that you already have a thing for her :/ Sometimes you could be the nicest person to someone and they still may not like you for whatever reason. I say, delete the request and don't talk to her next time or just smile politely and walk away. Focus your attention on another girl because for her own reasons she's not accepting it.
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I see two possibilities:
1. She can't tell its you from your Instagram profile (maybe you have a confusing username or picture)
2. Or she doesn't want to be in touch with you.
If it is this second one, she's not worth your time.
Good luck :)
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