Why is his reply different to when being asked if we are dating?

So my friend and I like to bicker and tease each other often, at the same time he seems to get annoyed with me easily and distant. When we are out we get asked if we are dating, to which we both put a lot of emphasis on it and are like Nooo!, we also get asked if we are siblings sometimes too which we reply no that would be weird, as we have slept together once over a year ago, (he didn’t want to do it again and I had feelings for him which have decreased) but he feels the need to explain why especially if it’s with a guy I’ve been flirting with…

last night we were out and someone asked him and our friend if they were together, which they both replied calmly ‘no, just friends’. Why does he have to be dramatic with me when asked that question? But calmer with her?
Why is his reply different to when being asked if we are dating?
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