I think that all depends on how much of a card your friend's brother is. If he was just putting out his cheek to mess around and didn't expect or want to kiss you it could have been an accident. Your friend pushed you into him, maybe he wasn't expecting it.
On the other hand it could be the exact opposite and he actually likes you. He hugged you before you left. To you just ask for a hug in a friendly way? If not then he might like you.
It really depends on how he acts as a person though. If this is the same kind of thing he would do around other girls I would stay skeptical... Although in my personal opinion it does sound like he likes you.
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yes he might like you, see where this goes
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