
Natalia Romanova was born in 1928. She started training at the age of 9 and was fighting in the second world war at the age of eleven. First trained by Wolverine himself and later by Bucky Barnes. She knows many different martial arts and is skilled with military weapons. She can lift up to 500 lbs and often dodges machine gun fire from a close range.

She has 80 years of fighting experience (which is 24 years more than Captain America). She can heal faster than Captain America and ages slower than him, allowing her to be in her prime for really long. She fought Wolverine and The Winter Soldier to a standstill before and defeated a mind-controlled Captain America. This was a bloodlusted Cap who wasn't holding back, but he also lacked most of his usual intelligence and didn't have the ability to think.

She's also the mother and mentor of Damian Wayne, who was the fourth Robin. She once challenged Batman to a sword fight to the death in the batcave.

Let's just say that this was the condition he ended up in but she barely had a scratch.

I think this would depend on the kind of fight. Black Widow takes this if they resort to hand to hand with no gear. She was given the super soldier serum and is stronger, faster, more durable, has better reflexes, and has picked up and thrown motorcycles at people.
It would be a lot closer with armed combat but I'd give the edge to Talia.
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