Why did my guy friend's new girlfriend ask me if I've been married or if I wanted kids?

PurpleStarGirl
I don't know if she was trying to get to know me or my other friend (not my guy friend) but I've never been asked them and they're kind of personal. I barely know her and she's not my friend.

Later on into the night, she also started asking about favorite comfort TV shows and when I mentioned I enjoyed Buffy The Vampire Slayer, she acted like she felt bad for me because I like that show. She also acted superior when my guy friend said he liked both Star Trek and Star Wars and said he couldn't like both. She also proceeded to install an application onto his Playstation without asking him (she doesn't live there and they've only been dating for about two weeks) and started playing her music without any consideration about anyone else's musical tastes (mine is completely different and is similar to my guy friend's).

She's a nice girl but those interactions were just odd and I'm just scratching my head over them.
Updates
+1 y
So they broke up and my friend went back to his ex who dumped him six years ago shortly afterwards and had hurt him deeply when they broke up. He's spoken about this ex girlfriend before and I've never heard good things about her. I still haven't. I don't get why someone would go back to someone who hurt you in the worst way possible in the past (he got sick with cancer, she left and previously made him rehome his dog). Exes are exes for a reason. Always will be my friend though.
Why did my guy friend's new girlfriend ask me if I've been married or if I wanted kids?
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